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Pyromancies are incredibly powerful spells that can ruin enemies’ health bar. In order to be able to use a pyromancy, you will need to have a Pyromancy Flame equipped in either hand, then at a bonfire, you can then attune any available pyromancy and use it as many times as is allowed
You can acquire a Pyromancy Flame from either as a starting gift by selecting the Pyromancy class at the start of the game, from Laurentius of the Great Swamp after rescuing him in The Depths or from Eingyi after gaining his trust
In total, there are 
19 pyromancies to collect throughout Lordran. 13 of which can be collected from 3 NPCs that have different requirements you’ll need to meet before they will sell you pyromancies. 4 are found at specific locations and 2 are acquired through various covenant tasks

The 3 NPCs you will need to find are

  • Laurentius of the Great Swamp
    Whom you can find in The Depths, from the start of the area, make your way down pass the Hollow enemies, go through the water then stay left to find a room with a lot of barrels in there. Roll through these barrels (don’t use physical attacks) to free Laurentius, he can then be found in Firelink Shrine, he will give you the Pyromancy Flame allowing you to cast pyromancies, ensure you purchase his pyromancies before going to Blighttown as speaking to the Daughter of Chaos, or holding a Chaos Pyromancy will send Laurentius hollow, meaning he will no longer sell you the pyromancies required
  • Quelaana of Izalith
    Is the most powerful pyromancer you can come across in the game, as such, she only sells pyromancies to those with a +10 or higher Pyromancy Flame, you can upgrade the Pyromancy Flame by selecting the option from Laurentius after freeing him, it will cost you souls to upgrade and to get to +10 you will require a total of 53,500 souls. You can find Queelana behind the large pillar just up and across the swamp behind the large pillar, talk to her and agree to her request to defeat the Bed of Chaos boss (Lost Izalith compulsory boss), ensure you have purchased all of Lurentius of the Great Swamps‘ pyromancies before talking with Queelana
  • Eingyi of the Great Swamp
    You can only purchase pyromancies from Eingyi providing you have been infected with an egg-head, this is possible in the Demon’s Ruins, attack an Egg-Carrier, allow them to infect you with a Parasite Egg, keep scratching your head (automatic) until your head burst into an egg, as soon as this happens, head to the Chaos Witch Queelags’ boss arena (Blighttown boss), then head down, go to the wall with the eggs (dead end). Attack this wall to reveal Eingyi, speaking to him whilst you have an “egg-head” will then allow him to sell you the pyromancies he carries, he will also sell you Egg Vermifuge, allowing you to cure your “egg-head” state
In addition to the NPCs, you can also find pyromancies throughout the world of Lordran as you make your way through the game as well as needing to collect 2 pyromancies from covenants 
Below, I will list off all 19 pyromancies in NPC order then the world drops and finally the covenants. You can use Pyromancies with any stats, they have no base requirement, except needing you to have the Pyromancy Flame equipped

Laurentius of the Great Swamp

  • Combustion, 500 souls
  • Fireball, 800 souls
  • Iron Flesh, 2000 souls
  • Flash Sweat, 2000 souls
  • Fire Orb, 8,000 souls

Queelana of Izalith

  • Great Combustion, 5,000 souls
  • Fire Whip, 10,000 souls
  • Undead Rapport, 10,000 souls
  • Great Fireball, 20,000 souls
  • Firestorm, 30,000 souls
  • Fire Tempest
    Queelana will gift you this pyromanncy after you have defeated the Bed of Chaos boss in Lost Izalith, alternatively, ensure you have collected every other pyromancy from Queelana then defeat her before defeating the Bed of Chaos, at which point, she will then drop the Fire Tempest pyromancy 

Eingyi of the Great Swamp

  • Poison Mist, 10,000 souls
  • Toxic Mist, 25,000 souls

World Loot

  • Power Within, Corpse, Blighttown
    On the wooden platforms above the swamp in Blighttown, will be a wall hugger enemy, go as far right as you can before descending down to the swamp, you need to defeat this thing (use pyromancies/firebombs/ranged/sorceries, anything but melee to have a much easier time of it), once you’ve defeated it, just pass where it was will be the Power Within pyromancy on the very edge of a wooden ledge 
  • Acid Surge, Corspe, Painted World of Ariamis
    Continue through Ariamis until you get to the Phalanx enemy, from here, open the double doors to be able to access the bonfire, from the Phalanx, head over to the left to find a graveyard in the snow, continue as far left as you can go, behind a wall on a corpse will be the Acid Surge pyromancy 
  • Fire Surge, Engorged Zombie, Painted World or Ariamis
    As above, except this time, from the Phalanx, head over to the right of the arena to find a well, descend the ladder, from here, proceed through the tunnels to find a set of stairs (from the ladder go forward, left, left, left, right, staircase) up here will be an Engorged Zombie, defeat this enemy to be able to loot the  Fire Surge pyromancy 
  • Chaos Fire Whip, Chest, Lost Izalith
    Proceed through Lost Izalith until you get to the Bed of Chaos boss fight fog gate, from here, continue around to the right at the end of the path will be a chest, inside this chest will be the Chaos Fire Whip pyromancy

Covenant Pyromancies

  • Great Chaos Fireball, Daughter of Chaos covenant
    You can join the Daughter of Chaos covenant by first getting to Blighttown, defeating Chaos Witch Queelag, then descending through the next area and hitting the illusionary wall at the end of the path. You will need to answer “Yes” to Eingyi, before you can join the covenant, if you have been following this guide, you will already have befriended Eingyi by becoming an “egg-head”, you can speak to the Daughter of Chaos, ask to join the covenant which, when accpeted will reward you with the Great Chaos Fireball pyromancy 
  • Chaos Storm, Daughter of Chaos covenant
    Once you have acquired the Great Chaos Fireball pyromancy, you will then need to acquire 30 Humanity (easily acquired by defeating the Rats in The Depths), once you have acquired 30 Humanity, head back to the Daughter of Chaos, offer the Humanity to her one at a time, once all 30 have been handed over, she will gift you the Chaos Storm pyromancy

That is all 19 pyromancies, once you have collected them all, your Trophy / Achievement will unlock

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